Hi @nihalm5930
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You desired use case is definitely achievable through the Use of the MFA API. To call the MFA API to manage enrollments you first need to Get MFA API access tokens. This documentation specifically states about your mentioned scenario:
If you are building a user interface to manage authentication factors, you’ll need to obtain a token you can use for the MFA API.
In order for you to send the users to your customized MFA page, you can use the Redirect with Actions extensibility, which allows you to redirect an user after they have authenticated with the user and password, but before MFA was triggered or tokens were issued. You can also check the schema for Redirect Actions for Partners for a better understanding of the flow.